Adele sported a classic look in a long black beaded gown.
"It's an honour to be nominated and terrifyingly wonderful to be singing in front of people who have captured my imagination over and over again. It's something I've never experienced and probably only ever will once," she said.
The track, which Adele co-wrote with Paul Epworth, has been nominated for Original Song, the first Bond theme to get the Oscar nod since 'For Your Eyes Only' in 1981.
It has already seen success, winning the Golden Globe Award for Best Original Song earlier this month.