Supermodel Kate Moss started throwing bread rolls at Enrique Iglesias after he serenaded her during one of his songs.
The singer was performing in Mexico and during his romantic tune "Hero", Enrique decided to show his affection for the British supermodel, who was one of the guests.
"Kate Moss. I used to have the biggest crush on you when I was a kid; be nice. I had your poster on my wall," he told her.
However, Kate wasn't impressed and started throwing things at him from her table, much to her friends' delight, reports contactmusic.com.
"She thought it was hilarious because he wasn't expecting her to react like she did. She threw the water first, then a few bread rolls and napkins. It was highly amusing and everybody was howling with laughter," a source told mirror.co.uk.
"She couldn't believe how lame he was and literally couldn't stop laughing as she did it. Her cackle was echoing around the room and everybody was watching with their mouths open as Kate threw whatever she could get her hands on at him," the source added.
Enrique saw the funny side of things and laughed along with the other guests.
Other guests at the luxurious bash for the British businessman included Naomi Campbell, Gwyneth Paltrow and Kate Hudson.