The clash of Lionel Messi and Barca with last year’s runners-up PSG is a repeat of their remarkable meeting at the same stage in 2017 when Barca overcame a 4-0 first leg loss to beat the French club 6-1 in Spain.
Martinez injured a left thigh muscle in the 3-3 draw against RB Leipzig on Saturday and will not play in their four remaining games this season in the Bundesliga and Champions League.
The defending champions, who won their first four matches and have already guaranteed first place in the group, will make the trip to Madrid without striker Robert Lewandowski, goalkeeper Manuel Neuer and midfielder Leon Goretzka.
Kingsley Coman scored one goal and set up another as Bayern Munich came from a goal down to beat VfB Stuttgart 3-1 on Saturday and stay top of the Bundesliga.
Warsaw prosecutors’ office spokesman Marcin Sadus said they ordered the detention of Cezary Kucharski as part of their investigation into Lewandowski’s report of criminal threats made against him.